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    温度对S135钢和G105钢在CO2/H2S共存体系中腐蚀行为的影响

    Effect of Temperature on Corrosion Behavior of S135 Steel and G105 Steel in CO2/H2S Coexisting System

    • 摘要: 在气体分压分别为20,0.1 MPa的CO2/H2S共存模拟油田地层水中,利用高温高压釜在不同温度(室温、100℃、180℃)下对S135钢和G105钢进行腐蚀试验,研究了温度对2种钢腐蚀行为的影响。结果表明:100℃下S135钢和G105钢的腐蚀速率最大,分别为0.846 3 mm·a-1和0.850 0 mm·a-1,180℃下的腐蚀速率最小,分别为0.229 1 mm·a-1和0.230 9 mm·a-1;100℃下钢表面腐蚀产物主要为FeCO3和FeS,此温度下CO2为腐蚀主控因素,室温和180℃下的腐蚀产物主要为FeS,H2S为腐蚀主控因素。

       

      Abstract: The corrosion tests of S135 steel and G105 steel were carried out by high temperature autoclaves at different temperatures (room temperature, 100 ℃, 180 ℃) in the simulated oil field formation water coexisted CO2/H2S gas with partial pressure of 20, 0.1 MPa, respectively. The influence of temperature on the corrosion behavior of the two steels was studied. The results show that the corrosion rate of S135 steel and G105 steel was the biggest at 100 ℃, reaching 0.846 3, 0.850 0 mm·a-1, respectively, while that at 180 ℃ was the smallest of 0.229 1, 0.230 9 mm·a-1, respectively. At 100 ℃, the corrosion products on the steel surface were mainly FeCO3 and FeS, and CO2 was the main controlling factor for corrosion. At the room temperature and 180 ℃, the corrosion products were mainly FeS, and H2S was the main controlling factor for corrosion.

       

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